I’m guessing the main fused spur for the heating is by the cylinder as well ?
Can you confirm what that grey wire does ?
No the Main Fused Spur is located next to the boiler in the kitchen (on the outside wall).
By Grey Wire I am guessing your asking about the wire that currently is wired into the L on Switched Line 1? If so, honestly I have no idea as there are 5 sets of grey outer sheathed wires (2Core+E & 3Core+E) when they finally exit the wall in the airing cupboard and are wired into the wiring centre.
I don't have the kit to easily test for continuity plus i'm not Gas Safe Cert'd so
technically shouldn't be popping front of boiler off and dropping wiring control centre in the boiler to gain access.
Putting those issues to one side I would have to jerry rig something (aka isolate, remove fuse, switch off MCB then run some wire from boiler to wiring centre location) to test for continuity to determine exactly which wire this is in the Wiring Centre.
But I think I get where your going with the question. If the grey wire exits into the wiring centre this could be repurposed as the Switched Line 2 as the L is simply a Live wire that could easily be replaced with another Live connection (or even just linked from the L to the right of it)
The system was almost certainly wired up like this originally (using Danfoss TPOneM (wired thermostat/programmer) and and TPOneB (wired thermostat). These were simply awful to use, even for me, and my elderly folks had no chance so were replaced with the Drayton Wiser Kit 3 by a sparky.
This is the current wiring centre attached to the Kingspan HW Cylinder along with the layout on the inside of the lid (when I mention Grey Sheathed Wires I am talking about Twin or 3 Core and Earth, some of the wires inside these also have grey sheaths)