My son has a Boulter Buderus Gas boiler and today he noticed water coming out of the vent outside having switched the heating on. I assume it is the pressure relief valve operating so I asked what the boiler pressure was....5 Bar! No wonder it was venting! So once it was cold and boiler inactive I asked him to bleed the nearest rad (bathroom) and he reduced it from 2.2 Bar to 1 Bar (cold). This he did but the pressure rose back up to 2.2 Bar. He has confirmed the filling loop is closed. Any suggestions as to what is going on? Boiler is in cupboard off bathroom and is highest part of the system.