Rather than start a new thread, I thought I'd piggy back on this one as I have a similar problem...
I have a Grant Vortex Utility 15-26 Oil Boiler and a Range Tribune Cylinder and controls. For reasons best only known to the person (no names!) both the boiler and the cylinder were specified and installed as system units meaning I initially had two pumps and two pressure vessels. After some time I finally managed to get Grant Technical Support to agree that this wasn't a terribly good idea, so I removed the pump and pressure vessel from inside the boiler casing.
All worked well for a number of years (the system was installed in 2007) and the boiler is serviced every year by a qualified Engineer. We've never been really happy about the heating output in this house so 18 months ago I got the Engineer to replace the burner nozzle with the a bigger size to bring the boiler up to its maximum output, making any other adjustments to the burner to suit.
The system has always had a very intermittent problem with the 110C overheat thermostat tripping out, but until recently this could be kept to a very occasional event by turning the boiler thermostat down slightly. This isn't helping with the shortage of heat, of course! So recently the overheat thermostat started tripping out more often, especially when I had the boiler thermostat full on. I replaced the overheat thermostat (Grant VBS147) with a new one, but somewhat to my annoyance the new one tripped out too! Thinking I had a faulty unit I removed it for further testing and wired the old one back in temporarily, but I also took the precaution of tucking a thermocouple down the side of the boiler pocket where the thermostat bulb went.
This is the point where my story begins to merge with the OP's - somewhat to my surprise I found that after the room stat had turned off, thus stopping the boiler and circulating pump, the residual heat in the boiler caused it to gradually creep up to 110C over the course of several minutes - so the overheat stat was doing the right thing after all.
So, what to do - having found this thread, I decided that I needed to arrange a pump overrun to cool the boiler down somewhat after the burner had been switched off.
Firstly is there a view about whether it's better to control the overrun with a timer or a pipe stat?
Secondly, it seems unlikely that pumping the water round a fairly short length of piping, via the automatic bypass, isn't going to achieve much cooling, so what I really need to do (I thought) was get one of the motorised valves (S- Plan) open as well to give the heat somewhere to go. On further thought it seems like using the cylinder coil would be the sensible choice as this problem might also happen in the summer when the heating is not on. Now this makes the wiring quite a lot more complicated, and at the moment I haven't worked out how to do it without at least one relay being involved as I have to stop the closed valve bringing the boiler back on again.
Has anyone worked out how to do this in as simple a way as possible? Using the time switch described above would give two sets of SPDT contacts, but I've not found a pipe stat with two contact sets, and I'm not yet sure if two is enough anyway!
Finally, I'm a retired Computer Programmer with an electronic Engineering degree, and as you can see I know a bit about how heating systems work, but I don't pretend to be a Heating Engineer! I mention this so you can use "dirty" words in any replies. Sorry this is so long...