No, the boiler has its own thermostat, set (mine) to 70C, so once the boiler is switched on from the roomstat then it will control the boiler/system water to 70C, the TRVs will control the flow rhrough their respective rads to give their requiredroom temperatures, obviously if the dining/living room roomstat is satisfied then the boiler switches off but because the settings are higher than the other room TRVs then generally these rooms are satisfied before the living/dining room is reached, I have the two rads in the living/dining rooms throttled/balanced as well which helps to achieve this, it works quite well. I would definitely though suggest installing a digital roomstat as it gives very tight control but I wouldn't go for anything too fancy like one with TPI control except that you can disable this feature.
As I said, mine has differential temperature control (set to 0.3C) so if the roomstat temp setpoint is 20C then it should swith off at 20C and switch back in at 19.7C but I've noticed that when the rooms are heated up that it seems to switch in at 19.9/19.8ish and switch off at 20C. I would think that all the well known manufacturers make this type, mine is a (less well known) FantiniCosmi.