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Tmv only on new. Replacing an existing doesn't need one. Do you have a shower or anything similar. Could be mains cold back feeding through cooling hot.
There is a separate mixer shower above the bath taps which seems to be fine.
 
I'm not at home to check the exact makes, I believe it's a Potterton, 1980's gas boiler and here's an image of the cylinder.

View attachment 38195

Check under bath and see if you have on of these.
Google Image Result for https://cdn.aws.toolstation.com/images/141020-UK/800/18520.jpg

If you don't have a TMV send a picture of bath taps and could you try get a clearer image of the cylinder and pipework later on, take a step back and include as much pipework as you can

Does anyone else see two pumps? Maybe a thermal store with a mixer on the side...
 
Thanks for all the advice and prompts. I’ve worked out there is a TMV on the cylinder pipework and think this might be the problem. I’ll let you know how I get on.
 

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