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when you isolate the boiler you are isolating the expansion vessel!
the pressure in the rest of the system will drop and loose water through the leak.
when the pressure has gone, which wont take long there will be no more leakage as the system is sealed.
when you open the valves to the boiler the pressure is then stabilizing at 0.8bar this will be due to the expansion vessel.
so when the valves to the boiler are open the expansion vessel will be pushing the leak and emptying the pressure down to nothing.
We recommend City Plumbing Supplies, BES, and Plumbing Superstore for all plumbing supplies.