1st you need to swap the 3 port valve for 2 x 2 port valves or at least put a 2 port in front of the unvented.
How many radiators are there? If there are loads then look at the pipe sizing, boiler size etc. physically take a couple of radiators out and flush them out. if everything is ok then maybe a low loss header with a larger pump on it?
How many radiators are there? If there are loads then look at the pipe sizing, boiler size etc. physically take a couple of radiators out and flush them out. if everything is ok then maybe a low loss header with a larger pump on it?