Post purging is interesting.
On the relatively large (50MW) oIl and gas fired boilers that I was very familiar with, we used oxygen analyzers for combustion control, normally 1.5% to 3%, depending on boiler output. Two oxygen analyzers were used. A post purge only occured if the boiler tripped on either flame failure or if both analyzers fell to 0.2% which meant combustion conditions was getting close to fuel rich conditions. If we requested a normal boiler stop, no post purge took place.
I am not so much concerned about the gases etc with enabling post purge, more so the oil side to make sure the boiler is shutting down correctly each time. I think the oil popping issue may be related to that.
I gave the boiler a perm live tonight and it is now shutting down correctly. The post purge is about 15 seconds roughly. Will be interesting to see if the oil popping noise is gone tomorrow morning on first start up.