From where your cold feed enters to the garage,then pump and boiler is this a long horizontal run of pipe work to the boiler? Any air vents/thumb vents if so on this run? Definately just sounds like an airlock which can be stubborn as f@£k sometimes.Try running the system an slightly cracking one of the pump valve unions to the pump with a bucket or rubble sack to see if you can clear air from the pump/pipe work this way
Also remove the pump head (pump valves isolated) an check the impellers, if half full of sludge use pin or pair tweezers to rod through every impeller to make sure it’s clear an the pump is actually circulating
Also remove the pump head (pump valves isolated) an check the impellers, if half full of sludge use pin or pair tweezers to rod through every impeller to make sure it’s clear an the pump is actually circulating