Yes it could in theory as it is an old enamelled steel type cylinder which I bet has not had the anode replace. If the internal heat exchanger has rusted the higher pressure domestic water could be leaking into the heating water raising the pressure so the heating safety valve discharges at 3bar.
As per other, get a good G3 engineer in (& disconnect that filling loop as per Water Regs).
As per other, get a good G3 engineer in (& disconnect that filling loop as per Water Regs).
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