Just thought I would post an outcome.
I was worried about running the boiler with the system valves closed so just disconnected condensate drain, connected it to a receptacle and left the boiler pressurised to 2.5 atmospheres. Over 6 hours there was a tiny pressure drop and a small drain of water. Repeated the process and this time no drop, no leak. I still felt it was likely the HE was leaking, probably most noticeable when hot, so from advice here thought I would give Ideal a try.
I don't quite understand the system, but with 300 quid over 6 months through domestic and general they would repair any fault on the boiler and guarantee it for the 6 months.
So decided to go with this. Engineer sent next day, stripped boiler, to my relief showed me the knackered HE and replaced it, with a general clean. Apparently the 300 quid is the cost of repair whatever it is, minor or major, so I presume d&g hope we will forget to cancel at 6 months and carry on with some exorbitant contract, note to diary.
In all I am very happy to have the 300 quid fix on an 8 year old boiler which in other respects has functioned well.
Lastly, sorry to have stimulated some flaming over the leak replenishment system: from an amateur viewpoint I would only like one fitted if it was able to give some indication of excessive replenishment or there could be masking of a fault and possible dilution of inhibitor