The only thing to add to Sam's post, which was more eloquently put than mine anyway, is that the old rads where probably sized on a MWTemp of 76.5deg C so to be able to get the most out of the boiler in condensing mode if new we would use max of 60 deg (& even a bit lower if there is no domestic hot water heating involved).The rads are sized for heat loss at -3 usually so as the the outside temp rises the demand is less, hence the flow temp can drop and the output can reduce.
The difference with lower flow temps are the heat exchange rate is a lot slower so you can't flick the heating on at 5pm and expect to be toasty by 5.30pm if your looking to raise the room temp by 3 or 4 degrees.
Maybe try and set the off temperatures to say 19 degrees through the day and if required the boiler can top up over the day. The problem might be where you have doors opening and closing all the time and heat loss that way.
As you say stradtobudy I thing you are asking a lot from the new boiler it is as the say summer, Ha, Ha !! Turn the heating off & when it gets a little colder turn it back on, set it up, leave it on & don't fiddle with it (& the WC system), at least for a while.