Looked at this on Saturday, gave it a lot of thought. Clearly Vent is in wrong place and this muct be where airs is coming from, but this is just pushed to the Bathroom radiator where it coolects. It can't get to th boiler. So bad installation by origional plumber but can't be why boiler is erroring. Also 3 way valve, yep agree too small for boiler on max, but if this were the problem I would get problems with radiators not gettinmg not enough. So would be a good upgrade but probably not causing bolier to error. It would just act like sevetral TRV's backing off.
So last idea is down rate the boiler as it's heating up too quickly. Okay, the only time the boiler errors is on start up, once it gets going its fine. So I down rated central heating to 27kW.
Well since then it's been fine, no problems at all. I have left the hot water at 40kW. The radiators are not as hot as they were and the house is on the edge of just being warm enough, so I might tweek to 30kW at the weekend if it behaves itself.
So my advise to anyone who gets an E9 error is down rate it as your very first jobas it only takes 2 minutes.
Thanks for all the advice guys 🙂