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3.843p / kWh
24.56p standing charge per day

So, let's estimate that your heating was on for 2 * 7-hour periods during the 36 hour it cost £5. That means that while the heating as on it was consuming:

(500 p - 36/24 *24.56 p) / (3.843 p / kW hr) / ( 2* 7 hr ) = 8 kW

You would need about 6 hot radiators (4 ft W * 2ft H) blasting away to dissipate that much heat, more than I'd expect for a small flat with reasonable insulation at this time of year.

So, I wonder if you have a dripping hot-water tap or possibly a leak somewhere. This would explain your observation that the boiler is continually firing up throughout the night.
 
The boiler doesn't do that any more now that it's off during the night.

And no dripping taps.

5 rads in total in flat. Living Room, kitchen, bedroom, bathroom and hall. They are all single except for the living room which is a double.

The only other time something would be using gas is when the oven is on for dinner.
 
5 rads in total in flat. Living Room, kitchen, bedroom, bathroom and hall. They are all single except for the living room which is a double. The only other time something would be using gas is when the oven is on for dinner.

The gas oven is only going to be less than 10% of the total.

8kW for 7 hours a day is on the high-side but not impossible particularly if the adjacent flats are unoccupied.

It's possible that the meter is actually charging you more than 3.8p/ kW hr so you need to find out what volume of gas it is recording.

The explanation could simply be that you are living in a flat with very high heat losses and the rent should be lower to reflect this.

The only way to be sure would be to get a heating engineer to do a heat loss calculation, check the calibration of the meter and that system is operating correctly.
 

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